"L.A. Ink" star Kat Von D and Sandra Bullock's ex Jesse James made their first public appearance together last night.

The couple, who was first spotted together in Vegas last month, went to the opening of Kat's Wonderland gallery together on Thursday in West Hollywood -- where they were all over each other.

At the event, Kat told PEOPLE she "doesn't hang out with anybody unless I'm in love" -- and added she believed James was "The One."

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