On "Glee," you saw him perform as Blaine with show brother Matt Bomer, now hear (and see!) Darren Criss sing with his real life brother Chuck!

The supremely talented siblings teamed up for a cover of Bob Dylan's "New Morning," one of the tunes featured on the four-disc compilation CD "Chimes of Freedom: Songs of Bob Dylan Honoring 50 Years of Amnesty International." Released in January, proceeds from sales benefit the human rights organization Amnesty International.

In this brand new video, check out behind-the-scenes footage of Darren recording the single with big brother Chuck, bass player for the band Freelance Whales. They definitely make one swoon-worthy pair!

The album and single are available now for download on iTunes.