The table read was initially delayed due to technical difficulties and then again so as to not conflict with the Democratic National Convention.
Pitt and Aniston were married from 2000 to 2005 and were once considered one of Hollywood's biggest celebrity couples. They have each remarried and divorced since -- Pitt with Angelina Jolie and Aniston with Justin Theroux.
You can catch Pitt and Aniston acting together for the first time since an episode of "Friends" when the table read broadcasts this Friday at 9 p.m. ET on CORE’s Facebook page and TikTok, as well as a stream via LiveXLive.